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acidity function

Also contains definitions of: basicity function, Hammett acidity function

Any function that measures the thermodynamic hydron-donating or -accepting ability of a solvent system, or a closely related thermodynamic property, such as the tendency of the lyate ion of the solvent system to form Lewis adducts. (The term 'basicity function' is not in common use in connection with basic solutions.) Acidity functions are not unique properties of the solvent system alone, but depend on the solute (or family of closely related solutes) with respect to which the thermodynamic tendency is measured. Commonly used acidity functions refer to concentrated acidic or basic solutions. Acidity functions are usually established over a range of composition of such a system by UV/VIS spectrophotometric or NMR measurements of the degree of hydronation (protonation or Lewis adduct formation) for the members of a series of structurally similar indicator bases (or acids) of different strength: the best known of these functions is the Hammett acidity function H 0 (for uncharged indicator bases that are primary aromatic amines).
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1081
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.A00081.
Original PDF version: http://www.iupac.org/goldbook/A00081.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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