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activation energy (Arrhenius activation energy)
An empirical parameter characterizing the exponential temperature dependence of the rate coefficient, Math - text, Math - ei, where Math - text is the gas constant and Math - text the thermodynamic temperature. The term is also used for threshold energies in electronic potential surfaces, in which case the term requires careful definition.
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See also:
PAC, 1996, 68, 149 (A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)) on page 151
PAC, 1993, 65, 2291 (Nomenclature of kinetic methods of analysis (IUPAC Recommendations 1993)) on page 2294
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1112
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: doi:10.1351/goldbook.A00102.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/A00102.pdf.
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