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activity coefficient, Math - title, Math - title
The activity coefficient Math - text of a substance B in a liquid or solid mixture containing mole fractions Math - text, Math - text, ... of the substances B, C, ... is a dimensionless quantity defined in terms of the chemical potential Math - text of B in the mixture by:
Math - e
where Math - text denotes the set of mole fractions Math - text, Math - text, ... . The activity coefficient Math - text of a solute B in a solution (especially a dilute liquid solution) containing molalities Math - text, Math - text, ... of solutes B, C, ... in a solvent A is a dimensionless quantity defined in terms of the chemical potential Math - text by:
Math - e
Source:
PAC, 1994, 66, 533 (Standard quantities in chemical thermodynamics. Fugacities, activities and equilibrium constants for pure and mixed phases (IUPAC Recommendations 1994)) on page 543
PAC, 1994, 66, 533 (Standard quantities in chemical thermodynamics. Fugacities, activities and equilibrium constants for pure and mixed phases (IUPAC Recommendations 1994)) on page 546
PAC, 1990, 62, 2167 (Glossary of atmospheric chemistry terms (Recommendations 1990)) on page 2171
PAC, 1996, 68, 957 (Glossary of terms in quantities and units in Clinical Chemistry (IUPAC-IFCC Recommendations 1996)) on page 960
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
DOI of this term: doi:10.1351/goldbook.A00116
Original PDF version (may be out of date): http://www.iupac.org/goldbook/A00116.pdf.
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