IUPAC > Gold Book > alphabetical index > A > adiabatic electron transfer
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adiabaticadiabatic ionization in mass spectrometry
adiabatic electron transfer
Electron transfer process in which the reacting system remains on a single electronic surface in passing from reactants to products. For adiabatic electron transfer the electronic transmission factor is close to unity.
See: Marcus equation
See also: diabatic electron transfer
Source:
PAC, 1996, 68, 2223 (Glossary of terms used in photochemistry (IUPAC Recommendations 1996)) on page 2227
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Cite as: IUPAC Compendium of Chemical Terminology, Electronic version, http://goldbook.iupac.org/A00142.html.
Transformed and rewritten from PDF version (entry http://www.iupac.org/goldbook/A00142.pdf)
by: Miloslav Nic, Jiri Jirat, Bedrich Kosata, ICT Prague, Czech Republic
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