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apical (basal, equatorial)
In trigonal bipyramidal structures (e.g. a five-coordinate trigonal bipyramid with phosphorus as central atom) the term apical refers to the two positions that are collinear with the central atom or to the bonds linking these positions to the central atom. The three equivalent bonds (or positions) in a plane passing through the central atom and perpendicular to the direction of the apical bonds are described as equatorial. (See axial, equatorial for alternative use). The term apical is also used for the bond pointing from the atom at or near the centre of the base to the apex of a pyramidal structure. The positions at or near the base of the pyramid, or the bonds linking those positions to the central atom of the base are described as basal. The apical bonds have also been called axial.
A00415
Source:
PAC, 1996, 68, 2193 (Basic terminology of stereochemistry (IUPAC Recommendations 1996)) on page 2199
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: doi:10.1351/goldbook.A00415.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/A00415.pdf.
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