If adsorption equilibrium and mutual
saturation of the phases is not achieved instantly, it is possible to distinguish the initial spreading tension,
, from the final spreading tension,
, when equilibrium has been reached. In the case in which
is positive, while
is negative, the system is said to exhibit autophobicity.
Source:
PAC, 1972, 31, 577
(Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry)
on page 598
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
doi:10.1351/goldbook.
