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characteristic X-ray emission

Also contains definitions of: fluorescence excitation
of X-rays
, primary excitation
of X-rays
, secondary excitation
of X-rays

Synonym: characteristic X-radiation

X-ray emission originates from the radiative decay of electronically highly excited states of matter. Excitation by electrons is called primary excitation and by photons, secondary or fluorescence excitation. Particle induced X-ray emission (PIXE) is produced by the excitation of heavier particles such as protons, deuterons or heavy atoms in varying degrees of ionization. Emission of photons in the X-ray wavelength region also occurs from ionized gases or plasmas at high temperatures, from nuclear processes (low-energy end of the gamma-ray spectrum) and from radiative transitions between muonic states. Characteristic X-ray emission consists of a series of X-ray spectral lines with discrete frequencies, characteristic of the emitting atom. Other features are emission bands from transitions to valence levels. In a spectrum obtained with electron or photon excitation the most intense lines are called diagram lines or normal X-ray lines. They are dipole allowed transitions between normal X-ray diagram levels.
Source:
PAC, 1991, 63, 735 (Nomenclature, symbols, units and their usage in spectrochemical analysis - VIII. Nomenclature system for X-ray spectroscopy (Recommendations 1991)) on page 737
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.C00985.
Original PDF version: http://www.iupac.org/goldbook/C00985.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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