IUPAC > Gold Book > alphabetical index > C > charge-transfer (CT) transition
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charge-transfer (CT) transition
An electronic transition in which a large fraction of an electronic charge is transferred from one region of a molecular entity, called the electron donor, to another, called the electron acceptor (intramolecular CT) or from one molecular entity to another (intermolecular CT). Typical for donor-acceptor complexes or multichromophoric molecular entities. In some cases the charge-transfer absorption band may be obscured by the absorption of the partners.
Source:
PAC, 1996, 68, 2223 (Glossary of terms used in photochemistry (IUPAC Recommendations 1996)) on page 2232
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Cite as: IUPAC Compendium of Chemical Terminology, Electronic version, http://goldbook.iupac.org/C01008.html.
Transformed and rewritten from PDF version (entry http://www.iupac.org/goldbook/C01008.pdf)
by: Miloslav Nic, Jiri Jirat, Bedrich Kosata, ICT Prague, Czech Republic
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