IUPAC > Gold Book > alphabetical index > C > chemical shift in photoelectron and Auger spectra
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chemical shift

in photoelectron and Auger spectra
The displacement of photoelectron or Auger peak energies originating from changes in electron binding energies as a consequence of differences in the chemical environment of the atoms.
Source:
PAC, 1979, 51, 2243 (General aspects of trace analytical methods - IV. Recommendations for nomenclature, standard procedures and reporting of experimental data for surface analysis techniques) on page 2247
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.C01037.
Original PDF version: http://www.iupac.org/goldbook/C01037.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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