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coherence length, ζ

in thin films

Also contains definitions of: electric coherence lengthin thin films, ξ E, magnetic coherence lengthin thin films, ξ M

The distance over which order is maintained. As an example, there can be long-range atomic or molecular order, i.e. coherence. Coherence lengths are significantly larger than molecular size. Normally, coherence length is estimated from electron, neutron or X-ray scattering and scales the size of ordered domains in material where long range ordering occurs (as in liquid crystals, for example). The term coherence length is also used for the scale characterizing the profile of molecular axis orientation in the distorted, so-called, transition layers formed at a solid/liquid-crystal boundary when an appropriate external field is applied (e.g. when the orientation of anchored surface molecules of a nematic liquid crystal is unaffected by an external field -- magnetic or electric -- whereas the bulk molecules reorient freely). This scale is referred to as electric coherence length, ζ E or magnetic coherence length, ζ M, depending on the nature of the applied field.
Source:
PAC, 1994, 66, 1667 (Thin films including layers: terminology in relation to their preparation and characterization (IUPAC Recommendations 1994)) on page 1675
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.C01129.
Original PDF version: http://www.iupac.org/goldbook/C01129.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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