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definitive method

A method of exceptional scientific status which is sufficiently accurate to stand alone in the determination of a given property for the certification of a reference material. Such a method must have a firm theoretical foundation so that systematic error is negligible relative to the intended use. Analyte masses (amounts) or concentrations must be measured directly in terms of the base units of measurements, or indirectly related through sound theoretical equations. Definitive methods, together with certified reference materials, are primary means for transferring accuracy, i.e. establishing traceability.
Source:
PAC, 1995, 67, 1699 (Nomenclature in evaluation of analytical methods including detection and quantification capabilities (IUPAC Recommendations 1995)) on page 1701
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.D01553.
Original PDF version: http://www.iupac.org/goldbook/D01553.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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