Sometimes
chain branching is brought about by an intermediate which has a long lifetime compared with an ordinary
free radical. If this intermediate can break down in different ways, only one of which leads to branching, there may be a relatively slow increase in the number of radicals, and there is said to be degenerate
chain branching.
Source:
PAC, 1996, 68, 149
(A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996))
on page 162
