An ion formed either when a chemical species exists in the vapour as a dimer and can be detected as such, or when a molecular ion can attach to a neutral molecule within the ion source to form an ion such as
[M2]+.
where
M
represents the molecule.
Source:
PAC, 1991, 63, 1541
(Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991))
on page 1549
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
doi:10.1351/goldbook.
