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electric potential difference, Δ V

of a galvanic cell
Difference in the potentials of electrodes on the right and left of a galvanic cell. When Δ V is positive, positive charge flows from left to right through the cell.
Note:
The limiting value of E cell for zero current flowing through the cell, all local charge transfer and chemical equilibria being established, was formerly called emf (electromotive force). The name electromotive force and the symbol emf are no longer recommended, since a potential difference is not a force.
Source:
PAC, 1996, 68, 957 (Glossary of terms in quantities and units in Clinical Chemistry (IUPAC-IFCC Recommendations 1996)) on page 971
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.E01934.
Original PDF version: http://www.iupac.org/goldbook/E01934.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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