IUPAC > Gold Book > alphabetical index > E > electrode reaction rate constants
icon
(opens in a new window)


Indexes

electrode reaction rate constants
The electrode reaction rate constants are related to the partial currents by
Math - e
Math - e
where Math - text and Math - text are the rate constants for the oxidizing (anodic) and reducing (cathodic) reactions respectively, Math - text is the charge number of the cell reaction, Math - text is the Faraday constant and Math - text is the geometric area of the electrode, the product Math - ei includes all the species Math - text which take part in the partial reaction, Math - text is the volume concentration of species Math - text and Math - text is the order of the reaction with respect to species Math - text. The conditional rate constant of an electrode reaction is the value of the electrode reaction rate constant at the conditional (formal) potential of the electrode reaction. When Math - text the transfer coefficient is independent of potential,
Math - e
where Math - text and Math - text are the anodic and cathodic transfer coefficients respectively, Math - text is the electric potential difference, Math - text is the conditional (formal) potential, Math - text is the stoichiometric number, Math - text is the gas constant and Math - text is the thermodynamic temperature. Similar rate constants can be defined using activities in place of concen trations in the first two equations, and the standard electrode potential in place of the conditional potential in the latter two equations. This type of rate constant is called the standard rate constant of the electrode reaction. The observable electrode rate constant is the constant of proportionality expressing the dependence of the rate of the electrode reaction on the interfacial concentration of the chemical species involved in the reaction.
Source:
PAC, 1974, 37, 499 (Electrochemical nomenclature) on page 515
PAC, 1980, 52, 236
Interactive Link Maps
First LevelSecond LevelThird Level
GraphGraphGraph
Cite as: IUPAC Compendium of Chemical Terminology, Electronic version, http://goldbook.iupac.org/E01961.html.
Transformed and rewritten from PDF version (entry http://www.iupac.org/goldbook/E01961.pdf)
by: Miloslav Nic, Jiri Jirat, Bedrich Kosata, ICT Prague, Czech Republic
picture