Potential drop across the mobile part of the double layer, that is responsible for electrokinetic phenomena.
is positive if the potential increases from the bulk of the liquid phase towards the interface
. In calculating the electrokinetic potential from electrokinetic phenomena it is often asumed that the liquid adhering to the solid wall and the mobile liquid are separated by a sharp shear plane. As long as there is no reliable information on the values of the permittivity
and the viscosity
in the electrical double layer close to the interface
, the calculation of the electrokinetic potential from electrokinetic experiments remains open to criticism. It is therefore essential to indicate in all cases which equations have been used in the calculation of .
It can be shown, however, that for the same assumptions about the permittivity
all electrokinetic phenomena must give the same value for the electrokinetic potential.
PAC, 1996, 68, 957
(Glossary of terms in quantities and units in Clinical Chemistry (IUPAC-IFCC Recommendations 1996))
on page 971
PAC, 1994, 66, 891
(Quantities and units for electrophoresis in the clinical laboratory (IUPAC Recommendations 1994))
on page 894
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook