IUPAC > Gold Book > alphabetical index > E > elimination
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elimination
The reverse of an addition reaction or transformation. In an elimination two groups (called eliminands) are lost most often from two different centres (1/2/elimination or 1/3/elimination, etc.) with concomitant formation of an unsaturation in the molecule (double bond, triple bond) or formation of a new ring. If the groups are lost from a single centre (α-elimination, 1/1/elimination) the resulting product is a carbene or a 'carbene analogue'.
See also: α-elimination
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1112
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Cite as: IUPAC Compendium of Chemical Terminology, Electronic version, http://goldbook.iupac.org/E02038.html.
Transformed and rewritten from PDF version (entry http://www.iupac.org/goldbook/E02038.pdf)
by: Miloslav Nic, Jiri Jirat, Bedrich Kosata, ICT Prague, Czech Republic
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