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enthalpy of wetting

Referred to unit of mass of the solid, the difference (at constant temperature) between the enthalpy of a solid completely immersed in a wetting liquid, and that of the solid and the liquid taken separately. It must be specified whether the solid in the initial state is in contact with vacuum or with the vapour of the liquid at a given partial pressure. Measurements of the enthalpy of wetting of a solid equilibrated with varying relative pressures of the vapour of a pure wetting liquid may be used to derive the differential enthalpy of adsorption of the vapour.
Source:
PAC, 1972, 31, 577 (Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry) on page 605
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.E02144.
Original PDF version: http://www.iupac.org/goldbook/E02144.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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