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erythro structures

in a polymer

Also contains definition of: threo structures in a polymer

The relative configuration at two contiguous carbon atoms in the main chain bearing, respectively, substituents a and b (a ≠ b), is designated by the prefix erythro or threo, as appropriate, by analogy with the terminology for carbohydrate systems in which the substituents are OH. Examples:
E02211
Similar systems in which a higher level of substitution exists may be treated analogously if the erythro or threo designation is employed to denote the relative placements of those two substituents, one for each backbone carbon atom, which rank highest according to the Sequence Rule.
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.E02211.
Original PDF version: http://www.iupac.org/goldbook/E02211.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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