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excitation-emission spectrum
The three-dimensional spectrum generated by scanning the emission spectrum at incremental steps of excitation wavelength (Math - ei axis = emission wavelength, Math - ei axis = excitation wavelength, Math - ei axis = emission flux) is called a (fluorescence, phosphorescence) excitation-emission spectrum (or EES). The spectra are particularly useful for investigating samples containing more than one emitting species. Corrected EES are obtained if (a) the emission is corrected for instrumental response with wavelength, and (b) the exciting radiation flux in photons Math - text is held constant for all excitation wavelengths.
Source:
PAC, 1984, 56, 231 (Nomenclature, symbols, units and their usage in spectrochemical analysis-Part VI: molecular luminescence spectroscopy) on page 242
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
DOI of this term: doi:10.1351/goldbook.E02249
Original PDF version (may be out of date): http://www.iupac.org/goldbook/E02249.pdf.
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