The ratio of a dimensional characteristic of a macromolecule in a given solvent at a given temperature to the same dimensional characteristic in the

state at the same temperature. The most frequently used expansion factors are: expansion factor of the mean-square end-to-end distance,

;
expansion factor of the
radius of gyration

;
viscosity expansion factor

where

and

are the intrinsic
viscosity in a given solvent and in the

state at the same temperature, respectively. Expansion factors defined by different dimensional characteristics are not exactly equal, nor need they have a constant ratio as a function of
relative molecular mass.
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