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fluorescence error

in spectrochemical analysis
Some samples are excited to fluorescence by the incident radiation beam. When added to the transmitted radiation beam this fluorescence results in an erroneous reading called the fluorescence error. It is particularly noticeable if the photodetector is situated close to the sample.
Source:
PAC, 1988, 60, 1449 (Nomenclature, symbols, units and their usage in spectrochemical analysis - VII. Molecular absorption spectroscopy, ultraviolet and visible (UV/VIS) (Recommendations 1988)) on page 1457
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2009-09-07; version: 2.1.5.
DOI of this term: doi:10.1351/goldbook.F02455.
Original PDF version: http://www.iupac.org/goldbook/F02455.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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