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geminate pair
Pair of molecular entities in close proximity in solution within a solvent cage and resulting from reaction (e.g. bond scission, electron transfer, group transfer) of a precursor that constitutes a single kinetic entity.
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1117
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
DOI of this term: doi:10.1351/goldbook.G02602
Original PDF version (may be out of date): http://www.iupac.org/goldbook/G02602.pdf.
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