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half-peak potential
In linear-sweep voltammetry, triangular-wave voltammetry, cyclic triangular-wave voltammetry, and similar techniques, the potential of the indicator electrode at which the difference between the total current and the residual current is equal to one-half of the peak current. This potential is attained in the interval in which the rate of the charge-transfer process, and hence the (absolute value of the) current, increase monotonically with time.
Source:
PAC, 1985, 57, 1491 (Recommended terms, symbols, and definitions for electroanalytical chemistry (Recommendations 1985)) on page 1502
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: doi:10.1351/goldbook.H02720.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/H02720.pdf.
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