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heat capacity of activation, Math - title
A quantity related to the temperature coefficient of Math - text (enthalpy of activation) and Math - text (entropy of activation) according to the equations:
Math - e
If the rate constant is expressible in the form
Math - e,
then:
Math - e
SI unit: Math - text.
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1120
PAC, 1996, 68, 149 (A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)) on page 168
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: doi:10.1351/goldbook.H02754.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/H02754.pdf.
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