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higher-order transition

Synonym: smooth transition

A general term used to describe a transition in which the first and second derivatives of the molar Gibbs energy or molar Helmholtz energy (or chemical potential) with respect to temperature and pressure are continuous, but derivatives of some higher order are discontinuous at the transition point. Synonymous with smooth transition.
Source:
PAC, 1994, 66, 577 (Definitions of terms relating to phase transitions of the solid state (IUPAC Recommendations 1994)) on page 583
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.H02822.
Original PDF version: http://www.iupac.org/goldbook/H02822.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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