IUPAC > Gold Book > alphabetical index > H > homoconjugation
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homochiralhomocyclic compounds
homoconjugation
  1. [obsolete] [obsolete] Association between a base and its conjugate acid through a hydrogen bond (B ... HB+ or AH ... A−). Homoassociation is a more appropriate term for this phenomenon.
  2. The orbital overlap of two π-systems separated by a non-conjugating group, such as CH2.
    See also: conjugate acid–base pair, conjugated system, homoaromatic
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1121
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Cite as: IUPAC Compendium of Chemical Terminology, Electronic version, http://goldbook.iupac.org/H02842.html.
Transformed and rewritten from PDF version (entry http://www.iupac.org/goldbook/H02842.pdf)
by: Miloslav Nic, Jiri Jirat, Bedrich Kosata, ICT Prague, Czech Republic
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