A situation in which the freedom of molecules of
adsorbate to move about the surface is limited.
Adsorption is immobile when
is small compared to
, the energy barrier separating adjacent sites. The
adsorbate has little chance of migrating to neighbouring sites and such adsorption is necessarily localized.
Source:
PAC, 1976, 46, 71
(Manual of Symbols and Terminology for Physicochemical Quantities and Units - Appendix II. Definitions, Terminology and Symbols in Colloid and Surface Chemistry. Part II: Heterogeneous Catalysis)
on page 76
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
doi:10.1351/goldbook.
