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in-out isomerism
Isomerism found in bicyclic systems having long enough bridges to allow the bridgehead exocyclic bond or lone pair of electrons to point either inside the structure or outside.
I03055-1
I03055-2
Source:
PAC, 1996, 68, 2193 (Basic terminology of stereochemistry (IUPAC Recommendations 1996)) on page 2210
InChI=1/C27H54N2/c1-4-10-16-22-28-24-18-12-6-2-7-13-19-25-29(23-17-11-5-1)27-21-15-9-3-8-14-20-26-28/h1-27H2
FXXCKCVFJMLVDF-UHFFFAOYAZ
InChI=1/C27H54N2/c1-4-10-16-22-28-24-18-12-6-2-7-13-19-25-29(23-17-11-5-1)27-21-15-9-3-8-14-20-26-28/h1-27H2
FXXCKCVFJMLVDF-UHFFFAOYAZ
InChI=1/C27H54N2/c1-4-10-16-22-28-24-18-12-6-2-7-13-19-25-29(23-17-11-5-1)27-21-15-9-3-8-14-20-26-28/h1-27H2
FXXCKCVFJMLVDF-UHFFFAOYAZ
InChI=1/C18H34O9/c1-5-22-13-17-14-24-7-3-20-4-8-25-16-18(15-23-6-2-19-1)27-12-10-21-9-11-26-17/h17-18H,1-16H2/t17-,18+
BTWGNOFALNYNBF-HDICACEKBT
InChI=1/C18H34O9/c1-5-22-13-17-14-24-7-3-20-4-8-25-16-18(15-23-6-2-19-1)27-12-10-21-9-11-26-17/h17-18H,1-16H2/t17-,18+
BTWGNOFALNYNBF-HDICACEKBT
InChI=1/C18H34O9/c1-5-22-13-17-14-24-7-3-20-4-8-25-16-18(15-23-6-2-19-1)27-12-10-21-9-11-26-17/h17-18H,1-16H2/t17-,18+
BTWGNOFALNYNBF-HDICACEKBT
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: doi:10.1351/goldbook.I03055.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/I03055.pdf.
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