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interparticle volume of the column, V 0

in chromatography
The volume occupied by the mobile phase between the particles in the packed section of a column. It is also called the interstitial volume or the void volume of the column. In liquid chromatography, the interparticle volume is equal to the mobile-phase hold-up volume (V M) in the ideal case, neglecting any extra-column volume. In gas chromatography, the symbol V G may be used for the interparticle volume of the column. In the ideal case, neglecting any extra-column volume, V G is equal to the corrected gas hold-up volume (V M o).
V G = V M o = V M j
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.I03116.
Original PDF version: http://www.iupac.org/goldbook/I03116.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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