IUPAC > Gold Book > alphabetical index > K > kinetic control of product composition


kinetic control

of product composition
The term characterizes conditions (including reaction times) that lead to reaction products in a proportion governed by the relative rates of the parallel (forward) reactions in which the products are formed, rather than by the respective overall equilibrium constants.
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1133
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.K03398.
Original PDF version: http://www.iupac.org/goldbook/K03398.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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