A procedure for replacing the discrete set of results obtained from an experiment by a continuous function. It is defined by the following.
For the set of variables

there are

measured values such as

and it is decided to write a relation:
where

are undetermined constants. If it is assumed that each measurement

of

has associated with it a number

characteristic of the uncertainty, then numerical estimates of the

are found by constructing a
variable 
, defined by

,
and solving the equations obtained by writing

except

.
If the relations between the

and

are linear, this is the familiar least-squares technique of fitting an equation to a number of experimental points. If the relations between the

and

are non-linear, there is an increase in the difficulty of finding a solution, but the problem is essentially unchanged.
Source:
PAC, 1981, 53, 1805
(Assignment and presentation of uncertainties of the numerical results of thermodynamic measurements (Provisional))
on page 1822
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
doi:10.1351/goldbook.