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mass-to-charge ratio, Math - ei in mass spectrometrymassic
mass-transfer-controlled electrolyte rate constant
In controlled-potential coulometry and related techniques, the empirically evaluated constant of proportionality defined by the equation
Math - e
where Math - symbol is the bulk concentration of the substance B, and Math - ei is the rate of change of that concentration, resulting from the consumption of B by reduction or oxidation at the working electrode.
Source:
PAC, 1985, 57, 1491 (Recommended terms, symbols, and definitions for electroanalytical chemistry (Recommendations 1985)) on page 1501
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: doi:10.1351/goldbook.M03755.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/M03755.pdf.
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