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metal–insulator transition

Synonym: metal–nonmetal transition

A transition characterized by a sudden change in electrical transport properties (conductivity) due to a reversible change from localized to itinerant behaviour of the electrons. Example: The transition at 339 K in VO2 where it changes from a high-temperature metallic behaviour to a low-temperature semiconductor behaviour. Synonymous with metal–nonmetal transition.
Source:
PAC, 1994, 66, 577 (Definitions of terms relating to phase transitions of the solid state (IUPAC Recommendations 1994)) on page 586
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.M03863.
Original PDF version: http://www.iupac.org/goldbook/M03863.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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