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molecular nucleation
in polymers
The initial crystallization of a small portion of a macromolecule, after which further crystallization is thermodynamically favoured. Molecular nucleation may give rise to a new crystal or increase the size of a pre-existing one.
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: doi:10.1351/goldbook.M03995.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/M03995.pdf.
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