A measurement of
circular dichroism of a material which is induced
by a magnetic field applied parallel to the direction of the measuring
light beam. Materials which are
achiral still exhibit
MCD (the
Faraday effect), since the magnetic field leads to the lifting of the
degeneracy of electronic
orbital and spin states and to the mixing of
electronic states.
MCD is frequently used in combination with
absorption and CD studies to effect electronic assignments. The three
contributions to the
MCD spectrum are the A-term, due to Zeeman
splitting of the ground and/or excited degenerate states, the B-term,
due to field-induced mixing of states, and the C-term, due to a change
in the population of molecules over the Zeeman sublevels of a
paramagnetic ground state. The C-term is observed only for
molecules with ground-state paramagnetism, and becomes intense at
low temperatures; its variation with field and temperature can be
analysed to provide magnetic parameters of the
ground state, such as
spin,
g-factor, and zero-field splitting.
Variable-temperature
MCD is
particularly effective in identifying and assigning electronic
transitions originating from
paramagnetic chromophores.
Source:
PAC, 1997, 69, 1251
(Glossary of terms used in bioinorganic chemistry (IUPAC Recommendations 1997))
on page 1283
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
doi:10.1351/goldbook.