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miscibility gap
Area within the coexistence curve of an isobaric phase diagram (temperature vs composition) or an isothermal phase diagram (pressure vs composition).
Note:
A miscibility gap is observed at temperatures below an upper critical solution temperature (UCST) or above the lower critical solution temperature (LCST). Its location depends on pressure. In the miscibility gap, there are at least two phases coexisting.
Source:
PAC, 2004, 76, 1985 (Definition of terms related to polymer blends, composites, and multiphase polymeric materials (IUPAC Recommendations 2004)) on page 1996
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: doi:10.1351/goldbook.MT07270.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/MT07270.pdf.
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