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narcissistic reaction [obsolete]

A chemical reaction that can be described as the conversion of a reactant into its mirror image, without rotation or translation of the product, so that the product enantiomer actually coincides with the mirror image of the reactant molecule. Examples of such reactions are cited under the entries fluxional and degenerate rearrangement.
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1144
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.N04086.
Original PDF version: http://www.iupac.org/goldbook/N04086.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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