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non-vertical energy transfer

Energy transfer process with a low Franck–Condon factor because the nuclear geometries of the minima on the ground- and excited-state potential energy surfaces of the donor or of the acceptor are strongly displaced.
Note:
A Franck–Condon transition is always vertical. Thus, it is not strictly correct to speak about non-vertical transition. However, the term implies that the projection of all the vibrational wave functions of the donor state onto all the vibrational functions of the acceptor will result in low Franck–Condon factors.
Source:
PAC, 2007, 79, 293 (Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)) on page 374
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.N04207.
Original PDF version: http://www.iupac.org/goldbook/N04207.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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