A non-linear isotherm can have several shapes, as classified by
Brunauer et al. In chromatography convex or concave shapes
are common, as well as combinations.
Source:
PAC, 1996, 68, 1591
(Nomenclature for non-linear chromatography (IUPAC Recommendations 1996))
on page 1593
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.