An isothermal, reversible reaction in the solid state, that, on cooling of a binary, ternary, ... ,

system, results in one, two, ...
(

) new solid phases. For example, in a binary system containing two solids

and
Synonymous with
metatectoid reaction.
Source:
PAC, 1994, 66, 577
(Definitions of terms relating to phase transitions of the solid state (IUPAC Recommendations 1994))
on page 588
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
doi:10.1351/goldbook.