photoionization detector
in gas chromatography
Radiation from an ultraviolet lamp ionizes certain species in the carrier gas. A potential difference is applied and the resulting ionization current is detected. The detector is only useful for substances with ionization potentials below about Math - text. This makes it quite useful for detecting one component of a combined eluent when the other component, for instance nitrogen, has a high ionization potential. The detector has a small linear dynamic range and is capable of detecting substances below Math - text.
Source:
PAC, 1990, 62, 2167 (Glossary of atmospheric chemistry terms (Recommendations 1990)) on page 2191