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photoionization detector
in gas chromatography
Radiation from an ultraviolet lamp ionizes certain species in the carrier gas. A potential difference is applied and the resulting ionization current is detected. The detector is only useful for substances with ionization potentials below about Math - text. This makes it quite useful for detecting one component of a combined eluent when the other component, for instance nitrogen, has a high ionization potential. The detector has a small linear dynamic range and is capable of detecting substances below Math - text.
Source:
PAC, 1990, 62, 2167 (Glossary of atmospheric chemistry terms (Recommendations 1990)) on page 2191
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: doi:10.1351/goldbook.P04621.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/P04621.pdf.
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