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A residue from pyrolysis of organic material or tar distillation which is solid at room temperature, consisting of a complex mixture of numerous, essentially aromatic hydrocarbons and heterocyclic compounds. It exhibits a broad softening range instead of a defined melting temperature. When cooled from the melt, pitches solidify without crystallization.
The ratio of aromatic to aliphatic hydrogen depends mainly on the source of the starting material. The hydrogen aromaticity (ratio of aromatic to total hydrogen atoms) varies between 0.3 and 0.9. The aliphatic hydrogen in pitch is largely associated with alkyl side chains substituted on aromatic rings. The content of heterocyclic compounds in pitches varies depending on their origins. Also, the softening temperature can vary in a broad range between about 320 and 570 K depending on the molecular weight (relative molecular mass) and composition of the constituents.
PAC, 1995, 67, 473 (Recommended terminology for the description of carbon as a solid (IUPAC Recommendations 1995)) on page 500
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.P04677.
Original PDF version: http://www.iupac.org/goldbook/P04677.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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