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polarizability
The ease of distortion of the electron cloud of a molecular entity by an electric field (such as that due to the proximity of a charged reagent). It is experimentally measured as the ratio of induced dipole moment (Math - symbol) to the field Math - symbol which induces it:
Math - e
The units of Math - symbol are Math - text. In ordinary usage the term refers to the 'mean polarizability', i.e., the average over three rectilinear axes of the molecule. Polarizabilities in different directions (e.g. along the bond in Cl2 , called 'longitudinal polarizability', and in the direction perpendicular to the bond, called 'transverse polarizability') can be distinguished, at least in principle. Polarizability along the bond joining a substituent to the rest of the molecule is seen in certain modern theoretical approaches as a factor influencing chemical reactivity, etc., and parametrization thereof has been proposed.
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1151
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Cite as: IUPAC Compendium of Chemical Terminology, Electronic version, http://goldbook.iupac.org/P04711.html.
Transformed and rewritten from PDF version (entry http://www.iupac.org/goldbook/P04711.pdf)
by: Miloslav Nic, Jiri Jirat, Bedrich Kosata, ICT Prague, Czech Republic
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