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primitive change

One of the conceptually simpler molecular changes into which an elementary reaction can be notionally dissected. Such changes include bond rupture, bond formation, internal rotation, change of bond length or bond angle, bond migration, redistribution of charge, etc. The concept of primitive changes is helpful in the detailed verbal description of elementary reactions, but a primitive change does not represent a process that is by itself necessarily observable as a component of an elementary reaction.
Source:
PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1152
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.P04845.
Original PDF version: http://www.iupac.org/goldbook/P04845.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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