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quarter-transition-time potential
In chronopotentiometry (at constant current density ), the potential of the indicator electrode at the instant when the time that has elapsed since the application of current is equal to one-fourth of the transition time. Appropriate correction for double-layer charging is needed in practice.
Source:
PAC, 1985, 57, 1491 (Recommended terms, symbols, and definitions for electroanalytical chemistry (Recommendations 1985)) on page 1502
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: doi:10.1351/goldbook.Q04992.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/Q04992.pdf.
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