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Rayleigh ratio
The quantity used to characterize the scattered intensity at the scattering angle Math - ei, defined as Math - ei, where Math - ei is the intensity of the incident radiation, Math - ei is the total intensity of scattered radiation observed at an angle Math - ei and a distance Math - ei from the point of scattering and Math - ei is the scattering volume. The factor Math - ei takes account of polarization phenomena. It depends on the type of radiation employed.
  1. For light scattering, dependent on the polarization of the incident beam, Math - ei for vertically polarized light, Math - ei for horizontally polarized light and Math - ei for unpolarized light.
  2. For small-angle neutron scattering, Math - ei.
  3. For small-angle X-ray scattering, Math - ei, if Math - ei.
Notes:
  1. The dimension of Math - ei is Math - ei.
  2. In small-angle neutron scattering the term cross-section is often used instead of Math - ei; the two quantities are identical.
  3. An alternative recommended symbol is Math - ei.
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Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2008-10-07; version: 2.0.2.
DOI of this term: doi:10.1351/goldbook.R05159.
Original PDF version (may be out of date): http://www.iupac.org/goldbook/R05159.pdf.
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