IUPAC > Gold Book > alphabetical index > R > reductones



Compounds containing an enediol structure stabilized by conjugation and hydrogen bonding with an adjacent carbonyl group, RC(OH)=C(OH)C(=O)R. They are strong reducing agents, fairly strong acids and commonly derived from saccharides by oxidation at the carbon atom alpha to the carbonyl function, e.g. ascorbic acid.
PAC, 1995, 67, 1307 (Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)) on page 1363
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IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. doi:10.1351/goldbook.
Last update: 2014-02-24; version: 2.3.3.
DOI of this term: doi:10.1351/goldbook.R05224.
Original PDF version: http://www.iupac.org/goldbook/R05224.pdf. The PDF version is out of date and is provided for reference purposes only. For some entries, the PDF version may be unavailable.
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