A name in which the replacement of an atom or a group of a parent structure by another atom or group is indicated by affixes attached to or inserted into the name of the parent structure. There are two main types of replacement names.
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Skeletal replacement name. A name in which the replacement of skeletal atoms and their associated hydrogen atoms is indicated by non-detachable prefixes. When carbon atoms are replaced by heteroatoms this method has been called 'a' nomenclature since the prefixes end in 'a'. Certain names in which the prefix 'thio-', 'seleno-' or 'telluro-' indicates replacement of a skeletal oxygen atom by a sulfur, selenium or tellurium atom, respectively, are also skeletal replacement names.
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Functional replacement name. A name containing prefixes or infixes which indicate the replacement of an oxygen atom or hydroxy group of a characteristic group, functional parent or class name by other atoms or groups.
Source:
Cite as:
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8.
doi:10.1351/goldbook.
